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Carboxylate Salt Formation. Taking advantage of this ring opening reaction. A small interlayer expansion 07 Å was observed with decanoic palmitic and sebacic acids which form the trapped carboxylate salts.
Ferent metal salts these resulted in the formation of metal carboxylate complexes16 The metallic magne-sium reacts with alcohols to give alkoxides which acts as nucleophile for ring opening reactions and maintains the pH suitable for formation of metal carboxylate com-plexes. An unexpected twist. Deprotonation to carboxylate ions is relatively easy but protonation more difficult.
Solutions formed in the reaction may be applied directly to a dry carrier.
A small interlayer expansion 07 Å was observed with decanoic palmitic and sebacic acids which form the trapped carboxylate salts. Taking advantage of this ring opening reaction. Carboxylic acids exhibit both acidic and basic character. Because of their enhanced acidity carboxylic acids react with bases to form ionic salts as shown in the following equations.